Bis(1,3-benzothiazol-2-amine-κN3)silver(I) nitrate acetone solvate
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چکیده
منابع مشابه
Bis(1,3-benzothiazol-2-amine-κN 3)silver(I) nitrate acetone solvate
In the title compound, [Ag(C(7)H(6)N(2)S)(2)]NO(3)·C(3)H(6)O, the Ag(I) ion is coordinated to two benzothia-zol-2-amine ligands via the thia-zole N atoms in an approximately linear arrangement. The dihedral angle between the mean planes of the two 1,3-benzothia-zole groups is 5.9 (3)°. Both amine groups on the ligands are oriented in the same direction and are engaged in N-H⋯O hydrogen bonding ...
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The Ni atom in the title compound, [NiCl(2)(C(12)H(10)N(2)O)(2)]·C(3)H(6)O, adopts a distorted octa-hedral geometry, being ligated by four N atoms from two different phenyl 2-pyridyl ketone oxime ligands and two Cl atoms. In the crystal structure, inter-molecular O-H⋯Cl hydrogen bonds link the mol-ecules into a chain structure along [010]. There is a π-π contact between the pyridine rings [cent...
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The title complex, [Cu(2)(C(13)H(18)N(2)O(3))(2)]·C(3)H(6)O, has been synthesized by the reaction of copper(II) acetate monohydrate with 5,5'-bis-(diethyl-amino)-2,2'-[ethyl-enedioxy-bis(nitrilo-methyl-idyne)]diphenol, where one of the N-O bonds of the ligand was cleaved during the reaction. The complex mol-ecule has a μ-dialkoxo-bridged binuclear structure with both Cu(II) centers exhibiting a...
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The title compound, 2[Ce(C(51)H(75)N(4)O(3))]·C(4)H(10)O, was obtained in high yield (92%) by reduction of (TRENDSAL)Ce(IV)Cl [TRENDSAL is N,N',N''-tris-(3,5-di-tert-butyl-salicyl-ide-natoamino)-triethyl-amine] with potassium in THF. The bulky tripodal TRENDSAL ligand effectively encapsulates the central Ce(III) cation with a Ce-N(imine) distance of 2.860 (2) Å and an average C-N(amine) distanc...
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In the title complex, [Mn(C(4)H(5)O(2))(C(27)H(27)N(7))(C(3)H(7)NO)]ClO(4)·C(3)H(7)NO, the Mn(II) ion is seven-coordinated in a distorted monocapped trigonal-prismatic geometry formed by a tetra-dentate tris-(1-methyl-1H-benzimidazol-2-ylmeth-yl)amine mol-ecule, a bidentate 2-methacrylate anion and a dimethyl-formamide mol-ecule. The methyl groups of the coordinated dimethyl-formamide mol-ecule...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s1600536809004176